The Foreign, Commonwealth and Development Office said those sanctioned were responsible for “undermining democracy, the rule of law, and human rights violations”.
Foreign Secretary David Lammy went on to describe Maduro’s regime as “fraudulent”.
Also on Friday, the EU said it was extending “restrictive measures” against Venezuela because of “the lack of progress… leading to the restoration of democracy and the rule of law”. The bloc also sanctioned a further 15 Venezuelan officials.
Maduro and his government have repeatedly denounced many of the allegations made by Western countries and opposition leaders. He has not yet commented on the most recent set of sanctions against him.
On Friday, President Maduro took the oath before parliament, vowing his third six-year term in office would be a “period of peace”.
“Tis new presidential term will be the period of peace, prosperity, equality, and the new democracy,” he said.
“I swear by history, I swear by my life, and I will fulfil it,” he added.
The 28 July election results were widely rejected by the international community, including by Brazil and Colombia, some of Venezuela’s left-wing neighbours.